Inrecentyearsthechoiceofagivensolventforperformingareactionhas
become increasingly important. More and more, selective reagents are used for
chemical transformations and the choice of the solvent may be determining for
reaching high reaction rates and high selectivities. The toxicity and recycling
considerations have also greatly influenced the nature of the solvents used for
industrialreactions. Thus, thedevelopmentof reactionsinwaterisnotonly
important on the laboratory scale but also for industrial applications. The per-
formance of metal-catalyzed reactions in water for example has led to several
new hydrogenation or hydroformylation procedures with important industrial
applications. The various aspects of organic chemistry in water will be present-
ed in this book. Recently, novel reaction media such as perfluorinated solvents
or supercritical carbon dioxide has proven to have unique advantages leading
to more practical and more efficient reactions. Especially with perfluorinated
solvents,newbiphasiccatalysesandnovelapproachestoperformorganic
reactions have been developed. These aspects will be examined in detail in this
volume.
Finally, theperformanceof reactionsintheabsenceof solventswillshow
practical alternatives for many reactions.
More than ever before, the choice of the solvent or the solvent system is essen-
tialforrealizingmanychemicaltransformationswiththehighestefficiency.
This book tries to cover the more recent and important new solvents or solvent
systems for both academic and industrial applications. |
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